Application

Sales of the core product, molecular-sieve pervaporation membranes, are made to the United States and the European Union.

Acetonitrile


Project Background

  Acetonitrile is an important organic chemical feedstock that is widely used as a solvent or reactant. During its production or recycling, it often needs to be separated from water. Because acetonitrile and water form an azeotrope with a boiling point of 76.3°C at atmospheric pressure—containing 84% acetonitrile by mass—conventional distillation cannot achieve effective separation. Current separation methods mainly include (salt‑added) extractive distillation, pressure‑swing distillation, and membrane permeation–vaporization dehydration.

Technical Comparison

Name

Membrane separation
(Membrane + atmospheric distillation for light-component removal)

Pressure-swing distillation
(Vacuum distillation + Pressurized distillation)

Steam (t/t raw material)

1.2

2.5

Circulating water (m³/t of raw material)

50

250

Low-temperature water (m³/t of raw material)

4

20

Chilled water (m³/t of raw material)

5

0

Electricity (kWh/t of raw material)

30

20

Operating cost (RMB/t of raw material)

287

580

Yield (%)

High, ≥97

Low, 90–93

Number of distillation columns (units)

1

2

Maximum operating pressure (MPa(G))

0.2

0.3~0.4

Required steam pressure (MPa(G))

≥0.4

0.6~0.7

Operational complexity

Simple, automatic control

Complex, multi-player operation

Equipment investment

Relatively high

Low

Annual operating costs (based on 10 m³ per day and 250 operating days per year, equivalent to 2,000 tons per year)

Energy consumption is reduced by RMB 600,000; the increased yield generates annual savings of over RMB 800,000 (based on an acetonitrile price of RMB 10,000 per ton), for total annual savings exceeding RMB 1.4 million.

 

Process Selection

Recommendation

Not recommended

 

 Acetonitrile